By Joseph S. Thrasher, Steven H. Strauss
Deals an updated account of primary and utilized study and issues to destiny instructions in inorganic fluorine chemistry. stories the most important advances in fluorine-containing substituent teams. offers a severe exam of coordination numbers more than six between fluorides and oxofluorides. Discusses makes an attempt to manage chemical reactivity and balance by using extra nucleophilic resources of fluoride or, conversely, extra weakly coordinating anions. gains chapters on new fluorine-containing ligands in organometallic, transition steel, stable country, lanthanide and actinide chemistry.
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Extra resources for Inorganic Fluorine Chemistry: Toward the 21st Century (ACS Symposium Series)
Engl. 1968, 7, 433. Emeleus, H. , "Advances in the Field of Fluorinated Inorganic Radicals," Allg. Prakt. Chem. 1968, 19, 1. Lawless, E. ; Rowatt, R. , "Review of Advanced Inorganic Oxidizers," Amer. Chem. Soc. 1968, 12, 108. Lawless, E. W; Smith, I. C. Inorganic High-Energy Oxidizers: Synthesis, Structure, and Properties; Marcel Dekker: New York, 1968. Mooney, E. ; Winson, P. , "Fluorine-19 Nuclear Magnetic Resonance Spectroscopy," Annu. Rev. NMR (Nucl. Magn. Resonance) Spectrosc. 1968, 1, 243.
If, for example, the absorption band at 220 nm reported by the Russian workers was photodissociative, then wavelengths in this region must be carefully filtered out if the yields are to be maximized. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1994. INORGANIC FLUORINE CHEMISTRY: TOWARD THE 21ST CENTURY 48 uncorrected for the decomposition of KrF during the course of the experiment (nominally 10-15 % per experiment).
Nikolaev, N. ; Buslaev, Υ. ; Ippolitov, E. , "Physicochemical Analysis in the Study of Inorganic Fluorides," In Zhavoronkov, Ν. M. "Nauka": Issled. Teor. Prikl. Neorg. Khim. 1971, 322, Moscow, USSR. , "NMR of Inorganic Solids: Applications to Some Solid Fluorides," Semin. Chim. Etat Solide 1971, 4, 33. Cady, G. , "Fluorides and Oxofluorides of Sulfur," Intra-Sci. Chem. Rep. 1971, 5, 1. Von Halasz, S. , "Sulfur-Fluorine Bond," In Sulfur Org. Inorg. ; Dekker: New York, 1971; p 209. Glemser, Ο. , "Sulfur-Nitrogen-Halogen Compounds," Int.