By Leonard R. MacGillivray
Metal-organic frameworks symbolize a brand new classification of fabrics which can resolve the hydrogen garage challenge linked to hydrogen-fueled autos. during this first definitive consultant to metal-organic framework chemistry, writer L. MacGillivray addresses state-of-art advancements during this promising expertise for substitute fuels. offering professors, graduate and undergraduate scholars, structural chemists, actual chemists, and chemical engineers with a ancient viewpoint, in addition to the main updated advancements through prime specialists, Metal-Organic Frameworks examines constitution, symmetry, supramolecular chemistry, floor engineering, metal-organometallic frameworks, homes, and reactions.
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Additional info for Metal-Organic Frameworks: Design and Application
The crystalline molecular flask is a nanometer-size container where a kinetic effect can be expected for chemical reactions. Moreover, a minimum amount of solvents and reagents is required for reactions. 37 Therefore, a porous organic coordination network can be called crystalline molecular flasks. 1 SCSC Chemical Transformation: Direct Observation of Unstable Imine The direct observation of unstable molecules that are difficult to isolate as crystals can be carried out by in situ preparation of labile compounds in a single crystalline state.
Interesting processes such as catalytic reactions, gas adsorption, and the formation of unstable species within the pore space of some coordination networks have been reviewed. Furthermore, cartridge synthesis of networks, which enables the design of pores with different environments, will make significant difference in molecular recognition, separation, and catalytic activity. Finally, we introduced the concept of crystalline molecular flasks using porous coordination networks, which will provide more opportunity to achieve new stereoselective reactions in pores and clarify reaction mechanisms.
Those materials are referred as monoporous coordination network. 1 mmol) as the bottom layer. 24 Crystal structure of [(ZnI2)3(TPT)2(2a)]Áx(nitrobenzene)Áy(methanol): (a) view of the interpenetrated networks along the b-axis, (b) two distinct channels A and B, (c) the infinite aromatic stacking between TPT and triphenylene at the inserted square in (a). material, triphenylene is considered as forming part of the host substructure rather than being a guest, since the intercalated triphenylene is not replaced by common aromatic compounds under guest exchange process due to the strong p–p stacking.