Organo- Transition Metal Compounds and Related Aspects of by B. L. /Tucker, N. I. Shaw

By B. L. /Tucker, N. I. Shaw

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Additional resources for Organo- Transition Metal Compounds and Related Aspects of Homogeneous Catalysis. ( = Pergamon Texts in Inorganic Chemistry Vol. 23)

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E. Fe(CO)4(olefin acid). 8]. 8] Maleic acid gives only a meso-ioxm. Chelating diolefins such as COD or NBD react with Group VI metal carbonyls to give compounds of the type M(CO)4(diolefin). Substitution is slow but may be promoted by ultraviolet light. The light induces loss of carbon monoxide and the diolefin can then attack the coordinatively unsaturated product. An interesting displacement of carbon monoxide 159 E. O. Fischer and K. Fichtel, Chem. Ber. 94 (1961) 1200. 160 G. Paiaro and R. Palumbo, Gazz.

The X-ray structure of Fe(CO)4(CH2:CHCN) shows that the C:C double bond is coordinated to the iron. Fe2(CO)9 will react with many olefins to give products of the type Fe(CO)4(olefin). With butadiene the product Fe(CO)4(C4H6) has only one of the double bonds coordinated. e. Fe(CO)4(olefin acid). 8]. 8] Maleic acid gives only a meso-ioxm. Chelating diolefins such as COD or NBD react with Group VI metal carbonyls to give compounds of the type M(CO)4(diolefin). Substitution is slow but may be promoted by ultraviolet light.

Formation by Displacement of Halide Ligands, Solvent or Weakly Coordinating Ligands such as Perchlorate or Nitrate The famous Zeise's salt, K[PtCl3(C2H4)],H20, first prepared in 1827, is made by shaking an aqueous solution of potassium chloroplatinate(II), containing hydrochloric acid, in an atmosphere of ethylene for several days. The yellow salt K[PtCl3(C2H4)],H20 crystallizes out. Propylene reacts similarly, but the reaction takes even longer. The reaction is catalysed by stannous chloride, which cuts down the reaction time from days to hours152.

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